Volumetric Analysis

IMPORTANT

Volumetric Analysis: Overview

This topic covers concepts, such as Redox Reactions as a Basis for Titrations, Volumetric Analysis, Titration, Titer, Titrant, Equivalence Point, End Point in Titration, Redox Titration, Simple Redox Titration, Redox Back Titration, etc.

Important Questions on Volumetric Analysis

MEDIUM
IMPORTANT

Number of moles of MnO4 is required to oxidise one mole of ferrous oxalate completely in an acidic medium will be:

MEDIUM
IMPORTANT

The reaction of   H 2 S with    H 2 O 2 is an example of _____________ reaction

MEDIUM
IMPORTANT

The reaction of H2S with H2O2 is an example of _____________ reaction.

EASY
IMPORTANT

The volume used for a definite amount of unknown reagent at its equivalence point is known as _____.

EASY
IMPORTANT

Define titre value.

MEDIUM
IMPORTANT

30 ml solution containing a mixture of Na2CO3 and NaOH required 20 ml of 1.5 N HCl for the phenolphthalein end point and in a separate titration 30 ml of the same mixture required 25 ml of same HCl when methyl orange used as an indicator for end point. Then find the ratio of number of moles of Na2CO3 to NaOH taken in the mixture.

EASY
IMPORTANT

The n factor for dichromate ion in a redox reaction with Mohr's salt in an acidic medium is

HARD
IMPORTANT

How many ml of 0.125 M Cr3+ must be reacted with 12.00 ml of 0.200 M MnO4- if the redox products are Cr2O72-and Mn2+?

MEDIUM
IMPORTANT

3.5 g of a mixture of NaOH and KOH were dissolved and made up to 250 ml. 25 mL of this solution were completely neutralized by 17 mL of (N/2) HCl solution. The percentage of KOH in mixture is:

MEDIUM
IMPORTANT

In the reaction Ca(OH)2+H3PO4 Ca PO423+H2O, the equivalent mass of H2O is: (M molecular mass)

MEDIUM
IMPORTANT

Which compound decolourises iodine solution?

MEDIUM
IMPORTANT

Consider the redox reaction 2S2O32-+I2S4O62-+2I-:

EASY
IMPORTANT

Which indicator will be most suitable for the titration of acetic acid vs NaOH?

HARD
IMPORTANT

25 ml  of household bleach solution was mixed with 30 ml of  0.50 M KI and 10 ml of  4 N acetic acid. In the titration of the liberated iodine, 48 ml of 0.25 N Na2S2O3 was used to reach the end point. The molarity of the household bleach solution is  

MEDIUM
IMPORTANT

Find out the percentage purity of KMnO4 if 2g impure sample of KMnO4 requires 40 ml of 0.5 M ferrous oxalate for complete reduction in acidic medium. 

HARD
IMPORTANT

The required volume (in litres) of 30 volume H2O2 in acidified medium required for decolourization of one mole of KMnO4 is:

MEDIUM
IMPORTANT

Calculate the moles of I- ion that are required to react with 1 mole of MnO4- in acidic medium?

EASY
IMPORTANT

Which of the following statements is incorrect for the reaction:

Excess of KI reacts with CuSO4 solution and Na2S2O3 solution is added to it.

MEDIUM
IMPORTANT

What is the volume (ml) of 0.05 M KMnO4 (acid) required to oxidize 2.0 g of FeSO4 in dilute solution?

MEDIUM
IMPORTANT

If 10 volume of H2O2 reacts completely with 100 ml of 2 N KMnO4, calculate the volume of H2O2 used in mL.